News & Research Highlights

Predrag Ranitovic dreams of controlling chemical reactions with ultrafast lasers. Now he and his colleagues in the Kapteyn/Murnane group are one step closer to bringing this dream into reality. The group recently used a femtosecond infrared (IR) laser and two extreme ultraviolet (XUV) harmonics created by the same laser to either ionize helium atoms or prevent ionization, depending on experimental conditions. The researchers adjusted experimental conditions to manipulate the electronic structure of the helium atoms as well as control the phase and amplitude of the XUV laser pulses.

Theoretical physicists recently combined two powerful tools for exploring ultracold atomic gases: Optical lattices and Feshbach resonances. Optical lattices are crystals of light formed by interacting laser beams. Feshbach resonances in an ultracold atom gas occur at a particular magnetic field strength and cause ultracold atoms to form very large, loosely associated molecules. However, because lattice atoms interact strongly at a Feshbach resonance, the physics of Feshbach resonances in an optical lattice is quite complicated.

The Lehnert group and collaborators from the National Institute of Standards and Technology (NIST) recently made what was essentially a CT scan of the quantum state of a microwave field. The researchers made 100 measurements at different angles of this quantum state as it was wiggling around. Because they only viewed the quantum state from one angle at a time, they were able to circumvent quantum uncertainties to make virtually noiseless measurements of amplitude changes in their tiny microwave signals. Multiple precision measurements of the same quantum state yielded a full quantum picture of the microwave field.

The semiconductor gallium arsenide (GaAs) is used to make tiny structures in electronic devices such as integrated circuits, light-emitting diodes, laser diodes, and solar cells that directly convert light into electrical energy. Because of GaAs’s importance to modern electronics, the Cundiff group seeks to understand the fundamental physics of its light-matter interactions on atomic and electronic levels.

The Lewandowski group recently decided to see what would happen if it could get cold molecules (1K–1mK) and ultracold (<1mK) atoms to collide. Former graduate student L. Paul Parazzoli, graduate student Noah Fitch, and Fellow Heather Lewandowski devised a novel experiment to determine the collision behavior of cold (100 mK) deuterated ammonia (ND₃) molecules and ultracold (600 microK) rubidium (Rb) atoms.

Triatomic hydrogen ion (H3+) has many talents. In interstellar clouds, it can be blown apart by free low-energy free electrons, which interact with the ion core (H3+), briefly forming unstable H3 molecules. The interaction of the electron with the ion core almost immediately causes the molecule to fall apart into three hydrogen atoms (3H) or a hydrogen molecule (H2) and an H atom. This reaction is known as dissociative recombination.

The dance of electrons as a bromine molecule (Br₂) separates into two atoms is intricate and complex. The process of breaking up takes far longer than expected (~150 vs 85 fs) because the cloud of electrons that bind atoms together in a molecule behaves as if it were still surrounding a molecule until the last possible moment — when the atomic fragments are about twice the normal distance apart (~.55 nm). At this point, there’s simply not enough energy left in the system to hold the molecule together. When the two atoms finally appear as separate entities, it was if someone had snapped a rubber band.

In 2008, the Ye and Jin groups succeeded in making ultracold potassium-rubidium (KRb) molecules in their ground state (See “Redefining Chemistry at JILA” in the Spring 2010 issue of JILA Light & Matter). Their next goal was to figure out how to precisely control chemical reactions of these ultracold polar molecules by manipulating the quantum states of the reactants. But first the researchers had to discover how to calm those reactions down enough to study them. Under the conditions in which they were made (an optical trap allowing motion in all three dimensions), ultracold KRb molecules were so chemically reactive they disappeared almost as soon as they were formed.

Putting the brakes on a superfluid dipolar Bose-Einstein condensate (BEC) just got a whole lot more interesting. Last year, the Bohn theory group explored what would occur in a dipolar BEC when a laser probe — think of it like a finger — tickled a BEC just hard enough to excite a roton.

In 2008-2009, much to their amazement,researchers working on the Jun Ye group’s neutral Sr optical atomic clock discovered tiny frequency shifts caused by colliding fermions! They figured out that the clock laser was interacting slightly differently with the Sr atoms inside a one-dimensional (pancake-shaped) trap. The light-atom interactions resulted in the atoms no longer being identical. And, once they were distinguishable, formerly unneighborly atoms were able to run into each other, compromising clock performance.

Hot Jupiters — giant gas planets orbiting close to their parent stars — aren’t just scorched (at temperatures of >1000 K). They are also swollen up larger than can be explained by the intense heat from their host stars. Recently Fellow Rosalba Perna and her colleagues from Columbia University and the Kavli Institute for Theoretical Physics suggested a reason why these planets are so puffed up: The swelling results from heat dissipated from electric currents generated by the interaction of robust magnetic fields (generated from deep within the giant planets) with strong atmospheric winds carrying charged particles called ions.

“Nature is built quantum mechanically,” says Fellow Jun Ye, who wants to understand the connections between atoms and molecules in complex systems such as liquids and solids (aka condensed matter). He says that the whole Universe is made of countless interacting particles, and it would be impossible to figure out the myriad connections between them one particle at a time, either theoretically or experimentally.

Graduate students or research associates at JILA have the option of signing up to help teach after-school science classes to elementary and middle school students in the St. Vrain School District. The volunteers expect to stimulate the children to learn to think critically, enjoy science activities, and become confident in their own abilities to master difficult concepts. What they may not anticipate at first is that they will learn some important skills themselves, including the ability to communicate scientific concepts in everyday language and, with that new ability, gain a better understanding of education.

The vision of a tabletop x-ray laser has taken a giant step into reality, thanks to Tenio Popmintchev, Ming-Chang Chen and their colleagues in the Kapteyn/Murnane group. By focusing a femtosecond laser into a gas, Popmintchev and Chen generated many colors of x-rays at once, in a band that stretched from the extreme ultraviolet into the soft x-ray region of the electromagnetic spectrum, spanning wavelengths of ranging from about 6 to 2.5 nm. This broad x-ray band has so many different colors that all the waves can be added together to form the shortest strobe light in existence.

The secret for reducing quantum noise in a precision measurement of spins in a collection of a million atoms is simple: Pre-measure the quantum noise, then subtract it out at the end of the precision measurement. The catch is not to do anything that detects and measures the spins of individual atoms in the ensemble. If states of individual atoms are measured, then those atoms stop being in a superposition and the subsequent precision measurement will be ruined.

Fellow Jun Ye’s group has enhanced the molecular fingerprinting technique with the development of a mid-infrared (mid-IR) frequency comb.  The new rapid-detection technique can now identify traces of a wider variety of molecules found in mixtures of gases. It offers many advantages for chemical analysis of the atmosphere, climate science studies, and the detection of suspicious substances.

Atomic force microscopy (AFM) just got a whole lot more efficient for studying proteins and other biomolecules. Graduate student Allison Churnside, former research associate Gavin King, and Fellow Tom Perkins recently used a laser to detect the position of sparsely distributed biomolecules on a glass cover slip. Since the same laser is also used to locate the AFM tip, it is now possible to align the microscope tip and sample with a precision of 40 nm, before the AFM tip even touches the sample. The researchers say that the new sample detection scheme solves the “needle in a haystack” problem of nanoscale microscopy.

Solvents don’t just dissolve other chemicals (called solutes) and then sit around with their hands in their pockets. Instead, they get involved in all sorts of different ways when dissolved molecules toss electrons around, i.e., they facilitate charge transfer events. In research, the hard part is fi guring out exactly how and when solvent molecules get involved when an electron hops from one solute molecule to another. For example, in liquids (which do most of the dissolving), solvent molecules move constantly, making it very challenging to see what they’re doing when charge transfer events occur.

In microscopic studies of single biological molecules or nanoparticles, it’s useful to be able to precisely control the temperature around the sample. Until now, heating has required electric currents that warm up microscope stages, slides, and optics in addition to the specimen under study. Such methods are slow and hard to control, not to mention capable of accidentally altering the chemistry or structure of the sample. Now there is a better solution for keeping samples nice and warm: The nanobathtub.

In 2008, the Deborah Jin Group introduced a new technique, known as atom photoemission spectroscopy, to study a strongly interacting ultracold gas cloud of potassium (40K) atoms at the crossover point between Bose-Einstein condensation and superfl uidity via the pairing of fermionic atoms (See JILA Light & Matter, Summer 2008). Near the crossover point, the physics of superfl uidity in an atom gas system may be connected to that of high-temperature superconductivity.