Dipole-dipole frequency shifts in multilevel atoms

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Dipole-dipole interactions lead to frequency shifts that are expected to limit the performance of next-generation atomic clocks. In this work, we compute dipolar frequency shifts accounting for the intrinsic atomic multilevel structure in standard Ramsey spectroscopy. When interrogating the transitions featuring the smallest Clebsch-Gordan coefficients, we find that a simplified two-level treatment becomes inappropriate, even in the presence of large Zeeman shifts.

Year of Publication
2021
Date Published
2021-06
Journal Title
Physical Review Letters
Volume
127
Issue
1
Start Page or Article ID
013401
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Imaging of dipolar frequency shift