TY - JOUR KW - pfc AU - L. Sinclair AU - Kevin Cossel AU - Tyler Coffey AU - Jun Ye AU - Eric Cornell AB - We have demonstrated a new technique that provides massively parallel comb spectroscopy sensitive specifically to ions through the combination of cavity-enhanced direct frequency comb spectroscopy with velocity-modulation spectroscopy. Using this novel system, we have measured electronic transitions of HfF+ and achieved a fractional absorption sensitivity of 3×10-7 recorded over 1500 simultaneous channels spanning 150  cm-1 around 800 nm with an absolute frequency accuracy of 30 MHz (0.001  cm-1). A fully sampled spectrum consisting of interleaved measurements is acquired in 30 min. BT - Physical Review Letters DA - 2011-08 DO - 10.1103/PhysRevLett.107.093002 N2 - We have demonstrated a new technique that provides massively parallel comb spectroscopy sensitive specifically to ions through the combination of cavity-enhanced direct frequency comb spectroscopy with velocity-modulation spectroscopy. Using this novel system, we have measured electronic transitions of HfF+ and achieved a fractional absorption sensitivity of 3×10-7 recorded over 1500 simultaneous channels spanning 150  cm-1 around 800 nm with an absolute frequency accuracy of 30 MHz (0.001  cm-1). A fully sampled spectrum consisting of interleaved measurements is acquired in 30 min. PY - 2011 EP - 093002 T2 - Physical Review Letters TI - Frequency Comb Velocity-Modulation Spectroscopy VL - 107 ER -