@article{4285,
  author = {Leah Dodson and Michael Thompson and J. Mathias Weber},
  title = {Interactions of Molecular Titanium Oxides TiOx (x=1-3) with Carbon Dioxide in Cluster Anions},
  abstract = {<p>We study small titanium oxide\textendashCO<sub>2</sub>\&nbsp;cluster anions\&nbsp;<em>in vacuo\&nbsp;</em>to understand the fundamental interactions between TiO<sub>x</sub>\&nbsp;and CO<sub>2</sub>\&nbsp;in the presence of an excess electron. Infrared spectra of [TiO<sub>x</sub>(CO<sub>2</sub>)<sub>y</sub>]<sup>-</sup>\&nbsp;(x\&nbsp;= 1\textendash3,\&nbsp;y\&nbsp;\&gt; 1) were obtained using photodissociation spectroscopy and assigned through quantum chemistry calculations, identifying the formation of carbonato, oxalato, oxo, η2-(O,O), and carbonyl ligands in the core ions of these clusters, with carbonato ligands being the dominant ligand species.</p>},
  year = {2018},
  journal = {The Journal of Physical Chemistry A},
  volume = {122},
  pages = {6909-6917},
  month = {2018-08},
  issn = {1089-5639},
  url = {https://pubs.acs.org/doi/pdfplus/10.1021/acs.jpca.8b06229},
  doi = {10.1021/acs.jpca.8b06229},
}